Pentaaqua(1H-benzimidazole-5,6-dicarboxylato-κN 3)copper(II) pentahydrate
نویسندگان
چکیده
The title compound, [Cu(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, contains one crystallographically independent Cu(II) atom and one 1H-benzimidazole-5,6-dicarboxyl-ate (bdc) ligand, along with five coordinated and five uncoordinated water mol-ecules. The Cu(II) atom is six-coordinated by one N atom from the bdc ligand and five O atoms from water mol-ecules, giving an octa-hedral coordination geometry. Hydrogen bonds link the mononuclear complex and uncoordinated water mol-ecules into a three-dimensional network.
منابع مشابه
Pentaaqua(1H-benzimidazole-5,6-dicarboxylato-κN 3)cobalt(II) pentahydrate
In the title mononuclear complex, [Co(C(9)H(4)N(2)O(4))(H(2)O)(5)]·5H(2)O, the Co(II) atom exhibits a distorted octa-hedral geometry involving an N atom of a 1H-benzimidazole-5,6-dicarboxyl-ate ligand and five water O atoms. A supra-molecular network is generated through inter-molecular O-H⋯O hydrogen-bonding inter-actions involving the coordinated and uncoordinated water mol-ecules and the car...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008